尹可锁, 张雪燕, 徐汉虹, 吴文伟, 代雪芳, 毛佳, 洪丽芳. 滇池周边大棚土壤中六六六和滴滴涕残留特征[J]. 中国生态农业学报(中英文), 2011, 19(2): 399-402. DOI: 10.3724/SP.J.1011.2011.00399
引用本文: 尹可锁, 张雪燕, 徐汉虹, 吴文伟, 代雪芳, 毛佳, 洪丽芳. 滇池周边大棚土壤中六六六和滴滴涕残留特征[J]. 中国生态农业学报(中英文), 2011, 19(2): 399-402. DOI: 10.3724/SP.J.1011.2011.00399
YIN Ke-Suo, ZHANG Xue-Yan, XU Han-Hong, WU Wen-Wei, DAI Xue-Fang, MAO Jia, HONG Li-Fang. Residue characteristics of HCHs and DDTs in greenhouse soils in Dianchi Lake Distract[J]. Chinese Journal of Eco-Agriculture, 2011, 19(2): 399-402. DOI: 10.3724/SP.J.1011.2011.00399
Citation: YIN Ke-Suo, ZHANG Xue-Yan, XU Han-Hong, WU Wen-Wei, DAI Xue-Fang, MAO Jia, HONG Li-Fang. Residue characteristics of HCHs and DDTs in greenhouse soils in Dianchi Lake Distract[J]. Chinese Journal of Eco-Agriculture, 2011, 19(2): 399-402. DOI: 10.3724/SP.J.1011.2011.00399

滇池周边大棚土壤中六六六和滴滴涕残留特征

Residue characteristics of HCHs and DDTs in greenhouse soils in Dianchi Lake Distract

  • 摘要: 采用气相色谱(ECD)对滇池周边不同年限大棚土壤中六六六(HCHs)和滴滴涕(DDTs)残留量进行了测定, 探讨其残留分布特征。结果表明: (1)大棚种植年限对土壤中残留量影响显著, 种植年限长于10 年的大棚土壤中HCHs 和DDTs 的残留量显著高于年限短于10 年的大棚, DDTs 是有机氯农药(OCPs)的主要组成成分;短于10 年的大棚间, 土壤中HCHs 和DDTs 残留量差异不显著。(2)不同土层中, HCHs 残留量在土壤剖面上的变化趋势不明显, 而DDTs 在表层土壤(0~20 cm)中残留量显著高于下层。(3)从HCHs 和DDTs 的同系物组成来看, HCHs 以β-HCH 残留量最高, 部分样点中p,p′-DDT/(DDD+DDE)比值大于1。可判断HCHs 残留主要是过去施用的残留物, 而DDTs 仍有新的污染输入, 有待进一步调查研究。

     

    Abstract: The characteristics of organo-chlorine pesticides (OCPs) were studied under greenhouse soil conditions. In the study, hexachlorocyclohexane (HCHs) and dichlorodiphenyl trichloroethane (DDTs) OCPs were analyzed using gas chromatography equipped with ECD detector. Soil samples were collected from 0, 1~5, 5~10, 10~15 and 15~25 years-old greenhouses at 0~20 cm, 20~40 cm and 40~60 cm soil profiles. Based on the study, mean HCHs and DDTs residue significantly increased in soil of greenhouses older than 10 years. HCHs and DDTs residues were not significantly different in 0~10 years-old greenhouse soils. DDTs were main component of OCPs residue. The trend in HCHs residue variation was not significantly different in different soil layers. However, DDTs concentration in the 0~20 cm surface soil was significantly higher than that in other soil layers. β-HCH concentration was higher than other HCH isomers in greenhouse soils. This suggested that the source of soil HCHs was residue of past applications. p,p′-DDT/(DDD+DDE) value in some soil samples was greater than one, suggesting that new DDTs were input in some of the greenhouses.

     

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